Defensive sets

The best way to start off would be to get anything with Armor as the core attribute. Regardless of the set, you'll be able to take more damage the more of this attribute you have, especially if one of your skills is a ballistic shield.

To take your build further, a list of the Armor-focused Brand and Gear Sets and what they specialize in are listed below:

Brand Sets

Set name Set bonuses
5.11 Tactical Health, incoming repairs, and hazard protection
Badger Tuff Shotgun damage, total armor, and armor on kill
Belstone Armory Armor regeneration, armor on kill, and incoming repairs
Gila Guard Total armor, health, armor regeneration
Golan Gear Ltd. Status effects, armor regeneration, and total armor

Gear Sets

Gear Set name Summary
Foundry Bulwark Specializes in total armor, armor regeneration and shield health regeneration. (This set's backpack and body armor can only be found in the Operation: Iron Horse raid.)
System Corruption Specializes in PVP-situational attributes, such as disrupt and pulse resistance and instant bonus armor. (This set can only be found in the Dark Zones.)
True Patriot Specializes in debuffing enemies, decreasing their damage and defense, as well as minor party armor regeneration.